Nucleation and growth of carbon nanotubes by microwave plasma. The nanotubes nucleate and grow from catalytic cobalt islands on a silicon substrate surface, with both their diameter and length dependent on the size of the cobalt islands. Pt nano particles were synthesized on carbon nanotubes cnts by chemical vapor deposition cvd. Carbon nanotubes cnt belong to a large group of hollow fiberlike carbon based nanomaterials with diameters mostly below 100 nm and very high aspect ratios. Hotwire chemical vapor deposition of carbon nanotubes a. Fisher1, euihyeok yang1 department of mechanical engineering, stevens institute of technology, castle pointonhudson, hoboken, nj 07030 usa. A systematic study of the temperature dependence of the growth rate and the structure of the asgrown nanotubes is presented using a c 2 h 2 nh 3 system and nickel as the catalyst. Cnt are of high technological interest because they can be produced or refined to possess specific properties such as high. Pdf chemical vapor deposition of methane for single.
Growth of singlewall carbon nanotubes by chemical vapor. Nucleation and growth of carbon nanotubes by microwave. Direct growth of carbon nanotubes on metal supports by. The paper reported the investigation of the substrate preparation technique involving deposition of iron catalyst by electron beam evaporation and ferrocene vaporization in order to produce vertically aligned multiwalled carbon nanotubes array needed for fabrication of tailored devices.
Jones national renewable energy laboratory, 1617 cole blvd, golden, co 80401, usa abstract hotwire chemical vapor deposition hwcvd has been employed for the continuous gasphase generation of both carbon. Understanding the nucleation mechanisms of carbon nanotubes. Chemical vapor deposition of methane for singlewalled carbon nanotubes. Chemical vapour deposition grown carbon nanotubes for. Hot wire chemical vapor deposition of isolated carbon.
Carbon nanotubes by plasmaenhanced chemical vapor deposition. This combined with the high operating temperature and pressure make this method highly inefficient for producing large amounts of carbon nanotubes. Synthesis of multiwalled carbon nanotubes mwnts was carried out by chemical vapour deposition, using three different precursors. Vertically aligned forests of large numbers of mwnts were achieved using ferrocene and iron phthalocyanine as precursors. Single wall carbon nanotubes synthesis through methane. In order to introduce each dopant into the graphitic carbon lattice, different precursors containing the doping elements benzylamine, pyrazine, triphenylphosphine, and methoxytrimethylsilane were added at various concentrations into.
Introduction carbon is known to be the most multipurpose element that exists on the earth. Chemical vapor deposition of methane for singlewalled. Hotwire chemical vapor deposition of carbon nanotubes. Current understanding of the growth of carbon nanotubes in catalytic chemical vapour deposition. Ethylene or pyrene was used in the cvd process with reactor temperatures of 545 c for nicatalyzed cvd and 900 c for the uncatalyzed. The next step was to grow singlewall carbon nanotubes. Carbon nanotubesnanofibers by plasma enhanced chemical. Chemical vapor deposition growth of carbon nanotubes. Synthesis of carbon nanotubes by catalytic chemical vapor. An indepth analysis of cnt synthesis based upon ceramic, noble metal, and semiconducting nanoparticle catalysts is. Nov 14, 2007 carbon nanotubes have been shown to posses a number of remarkable properties14. Experimental chemical vapour deposition of carbon nanotubes cj arendse1, gf malgas1, fr cummings1,2 and np cele1,3. Lowtemperature growth of carbon nanotubes by plasmaenhanced. A physical deposition method pvd to fabricate onedimensional nanoscale composites composite nanowires based on a coating of carbon nanotubes cnts with tungsten is presented.
Nano composites, multiwall carbon nanotubes, arc discharge, the laser ablation, chemical vapour deposition cvd 1. Jun 30, 2003 vertically aligned carbon nanotubes were grown at temperatures as low as 120 c by plasmaenhanced chemical vapor deposition. We report floating catalyst chemical vapour deposition synthesis of singlewalled carbon nanotubes swcnts for highperformance. Nanotubes using fastheating chemical vapor deposition.
Also nanospheres formation as additional or impurity growth of carbon nanotube and graphene. Li storage properties of carbon nanotubes prepared. Direct growth of carbon nanotubes on metal supports by chemical vapor deposition, carbon nanotubes synthesis, characterization, applications, siva yellampalli, intechopen, doi. Effect of catalyst particle size on the type of carbon nanotubes was determined. Current understanding of the growth of carbon nanotubes in. Direct growth of carbon nanotubes on metal supports by chemical vapor deposition naiqin zhao 1 and jianli kang 2 1school of materials science and engineering, tianjin univers ity, china tianjin key laboratory of composite and functional materials, tianjin, 2school of mechanical engineering, tianjin polytechnic university. The roie of the plasma in a cic plasma enhanced chemical vapor deposition system for carbon nanofiber growfi is. W vapor evaporating from a w filament is carried by h 2 gas to cnts and deposited along these cnts. The carbon nanotubes cnts formation by catalytic chemical vapor deposition is initiated by precursor decomposition to form a multitude of reactive species. The growth mechanism of long and aligned single walled carbon nanotubes using a recently reported fast heating chemical vapor deposition cvd method is discussed. Growth of singlewall carbon nanotubes by chemical vapor deposition for electrical devices. Li storage properties of carbon nanotubes prepared by.
The synthesis of carbon nanotubes cnts by catalytic laserinduced chemical vapor deposition clcvd was investigated. In this study we performed rutherford backscattering spectroscopy rbs and particle induced xray emission pixe analysis of impurity elements in carbon nanotubes cnts fabricated by chemical vapor deposition. Growing carbon nanotubes by microwave plasmaenhanced. Chemical vapor deposition of carbon nanotubes springerlink. Impact of different carrier gases hydrogen, argon and catalyst nickel, cobalt, iron on morphology of cnm was assessed. Synthesis of multiwalled carbon nanotubes by chemical vapour. Verticallyaligned carbon nanotubes vacnts were first reported by thess et al. We present the direct synthesis of graphene as well as carbon nanotube within the verticallyaligned carbon nanotube vacnt forests to form either the 3d cntgraphene or 3d cntcnt network by means of chemical vapor deposition cvd. Role of sulfur source on the structure of carbon nanotube. Singlewall carbon nanotube devices prepared by chemical. Sulfur and hydrogen radicals played important role in controlling the size of the catalyst nanoparticles. These three synthesis methods of cnt can be classified into two main categories depending on the growth.
Between them it is possible to produce nanotubes with differing properties and in different forms. Effect of hydrogen concentration on the growth of carbon. It was found that pyrolysis in presence of hydrogen produced more defined carbon nano beads 10 nm to 900 nm than with argon. Chemical vapour deposition of cnts using structural. Laser assisted chemical vapor deposition synthesis of carbon nanotubes and their characterization s.
As catalysts, fec composites of the coreshell type were used. Lowtemperature growth of carbon nanotubes by thermal chemical vapor deposition using pd, cr, and pt as cocatalyst cheol jin lee a, jeunghee park b, jae myung kim c, yoon huh c, jeong yong lee c, kwang soo no c a school of electrical engineering, kunsan national uni. Properties, synthesis, and growth mechanisms of carbon. Chemical vapor deposition of methane for singlewalled carbon. The nanotubes that are synthesized by this means are typically very ropy and multiwalled. Carbon nanotubes grown by catalytic co2 laserinduced. The optimum parameters for the growth and the micro. Synthesis and characterisation of carbon nano materials. Coating of carbon nanotubes with tungsten by physical vapor.
Singlewall carbon nanotube devices prepared by chemical vapor deposition p. Compared with other methods, chemical vapor deposition cvd is the most effective method that has broad prospects for largescale control of cnts in recent. On the growth and microstructure of carbon nanotubes grown by. Diameter analysis of the tubes produced by chemical vapor deposition cvd 3 and a tendency. Vapor deposition synthesis of carbon nanotubes shuhei inoue and shigeo maruyama department of mechanical engineering, the university of tokyo, 731 hongo, bunkyoku, tokyo 18656, japan the chemical reactions of transition metal clusters in the gas phase have aroused. We have fabricated singlewall carbon nanotubes by chemical vapor deposition from. Large scale production of multiwalled carbon nanotubes by. Additionally, we will report on the structure of cnts deposited by thermal cvd 3 using camphor as the carbon precursor. Growth of carbon nanotubes by chemical vapor deposition. In this study, a parametric study is implemented to solve this issue. Carbon nanotube fabrication at industrial scale arxiv. Such method is also a very important technique to in situ align carbon.
It was found that the diameter distribution of singlewalled carbon nanotubes swnts grown by the chemical vapor deposition cvd method could be controlled by the carbon feeding rate at the growth stage. Synthesis of multiwalled carbon nanotubes by chemical. Techniques have been developed to produce carbon nanotubes in sizable quantities, including arc discharge, laser ablation, highpressure carbon monoxide disproportionation, and chemical vapor deposition cvd. Chemical vapor deposition of pt nano particles on carbon. Largescale synthesis of singlewall carbon nanotubes by. Highperformance singlewalled carbon nanotube transparent. Chemical vapor deposition is a popular industrial method to grow carbon nanotubes because of the mass production at low cost.
Charlie johnson abstract carbon nanotubes cnts are an unusual, tubular form of carbon, composed of a lattice of. Li storage properties of carbon nanotubes prepared by chemical vapour deposition. The xray energy dispersive spectrum eds and electron energy. Continuous growth of singlewall carbon nanotubes using. Production of carbon nanotubes there are a number of known methods for producing carbon nanotubes. During largescale cnt selfassembly, these species vary with residence time leading to a nonuniform cnt growth. The process was catalyzed by cobalt nanoparticles produced via pyrolysis of a solid solution between cobalt and calcium tartrates. Cvd synthesis is achieved by taking a carbon species in the gas. International journal of research pharmaceutical and nano. Synthesis via chemical vapour deposition without hydrogen, surface modification, and application. The paper reports the application of a new method combining the plasma assisted chemical vapour deposition with the fluidized bed reactor principles for the production of carbon nanotubes on. School of mechanical engineering, georgia institute of technology, atlanta, ga 303320405, united states. These unique properties make cnts potentially valuable in a wide range of enduse applications. Growth of carbon nanotubes via chemical vapor deposition on.
Jun 21, 2012 this combined with the high operating temperature and pressure make this method highly inefficient for producing large amounts of carbon nanotubes. Chemical vapor deposition of carbon nanotubes on monolayer. Cvd system constructed at the csir for the deposition of cnts. Carbon nanotubes are regular carbon clusters with attractive mechanical and electronic pro. Schematic diagram of the chemical vapor deposition apparatus is shown in. Carbon nanotubesnanofibers by plasma enhanced chemical vapour deposition k. A unified hypothesis on the relationship between nanoparticle size, growth condition, growth temperature, and diameter of the resulting nanotubes was developed and. Synthesis of aligned carbon nanotubes using thermal. Presently, catalytic chemical vapor deposition cvd is the main preparation method for obtaining carbon nanotubes due to its many advantages. Chemical vapor deposition of methane for singlewalled carbon nanotubes jing kong a, alan m.
Present and future commercial applications michael f. During largescale cnt selfassembly, these species vary with residence time leading to a non uniform cnt growth. Properties, synthesis, and growth mechanisms of carbon nanotubes with special focus on thermal chemical vapor deposition. Chemical vapor deposition of carbon nanotubes on monolayer graphene substrates. John hart4,5 worldwide commercialinterest in carbon nanotubes cnts is reflectedin aproduction capacity that presently. Gruen materials science and chemistry divisions, argonne national laboratory, msdchm 200, argonne. Synthesized carbon nanotube cotton using floating catalyst chemical vapour deposition method. Growth of carbon nanotubes via chemical vapor deposition nsf summer undergraduate fellowship in sensor technologies alexei matyushov physics arizona state university advisors.
Currently, research into nanotubes and their applications is hampered by the lack of a suitable technique for manufacturing them. Although multiwall carbon nanotubes are now produced on an industrial scale 1, a detailed understanding of the synthesis mechanisms of single wall carbon nanotubes swnt is still mandatory for more elaborate applications 2. Trimethylmethylcyclopentadienyl platinum mecpptme3 was used as pt precursor, which was vaporized at 70oc and delivered to the pretreated cnts at the reactor. Chemical vapor deposition based synthesis of carbon. Effect of different catalyst deposition technique on.
The type of catalyst support is found to control the formation of individual23 or bundled swnts. Growth of carbon nanotubes via chemical vapor deposition. Clcvd uses both ex situ synthesized catalyst nanoparticles and the controlled decomposition of gasphase hydrocarbon mixtures. The effect of heating speed at the initial stage of the cvd process has been systematically studied, and a kitemechanism for the nanotube growth is proposed. The catalytic vapor phase deposition of carbon was reported in 1952 and 1959, but it was not until 1993 that carbon nanotubes were formed by this process. Carbon nanotubes have been shown to posses a number of remarkable properties14. Chemical vapour deposition cvd chemical vapour deposition is the method with the most promise for mass production of carbon nanotubes. Cassell a,b, hongjie dai a, a department of chemistry, stanford uni. The journal of physical chemistry c 2010, 114 45, 1918819193. Temperature effect on the growth of carbon nanotubes using. Selective chemical vapour deposition growth of carbon nanotubes on submicrometric ni patterns fabricated with scanning probe nanolithography digital instruments d5000 microscope nanoscope iv controller using commercial silicon tips frequency range 310370 khz scanned by means of a veeco nanoman closed loop xy head. Impurity elements study of carbon nanotubes fabricated by.
It is widely known that materials properties are very sensitive to the presence of impurity elements. In 2007, researchers at the university of cincinnati uc developed a process to grow aligned carbon nanotube arrays of length 18 mm on a firstnano et3000 carbon nanotube growth system during cvd, a substrate is prepared with. The kinetics of mwnt growth is fast and, with the catalyst used, no induction. Laser assisted chemical vapor deposition synthesis of carbon. Quantitative and controllable growth of carbon nanotubes on silicon carbide particles via chemical vapor deposition.
Synthesis of aligned carbon nanotubes using thermal chemical vapor deposition cheol jin lee a, dae woon kim a, tae jae lee a, young chul choi b, young soo park b, young hee lee b,c, won bong choi d, nae sung lee d, gyeongsu parke, jong min kim d a department of electrical engineering, kunsan national uni. This letter studies the selfassembly, and the reaction pathways leading. Controlling the diameter of carbon nanotubes in chemical. Chemical vapor deposition is suitable method to produce carbon nanostructures such as carbon nanotubes 8,9 and carbon nanospheres because its versatile technique. Abstract carbon nanotubes cnts were deposited on various substrates namely untreated silicon and quartz, fedeposited silicon and quartz, hftreated silicon, silicon nitridedeposited silicon, copper foil, and stainless steel mesh using thermal chemical vapor deposition technique. The nucleation and growth of aligned multiwall carbon nanotubes by microwave plasmaenhanced chemical vapor deposition have been studied. Carbon nanotubes cnt belong to a large group of hollow fiberlike carbonbased nanomaterials with diameters mostly below 100 nm and very high aspect ratios.
Selective growth of carbon nanotubes via photothermal. Lowtemperature growth of carbon nanotubes by thermal. A brief overview of the techniques reliant on the structural reorganization of carbon to form cnts is provided. In the same year, the chinese academy of science reported that a 50.
Chemical vapor deposition synthesis of n, p, and sidoped. Plasma enhanced chemical vapour deposition pecvd has been recently used for the production of vertically. Synthesis of carbon nanotubes by chemical vapor deposition cvd. This article highlights a recent advance in the fabrication of high. This approach entails chemical vapor deposition cvd based synthesis of carbon within the pores of an alumina template membrane with or without a ni catalyst. Lowtemperature growth of carbon nanotubes by plasma. Largescale synthesis of singlewall carbon nanotubes by catalytic chemical vapor deposition ccvd method j. It has previously been shown that carbon nanotubes can be grown by chemical vapour deposition cvd in such a way as to span gaps between catalyst particles5,6. Few cycle pulses in the bragg medium containing carbon nanotubes pdf. Li storage properties of carbon nanotubes prepared by chemical vapour deposition p. Mwnt have been produced very selectively on the multi gram scale by catalytic chemical vapor deposition from ethylene in a fluidized bed reactor. Carbon nanotubes cnts are crystalline, tubular, carbon structures with extraordinary mechanical, chemical, optical, and electrical properties. Growing carbon nanotubes by microwave plasmaenhanced chemical vapor deposition l. The cvd process uses hydrocarbons as the carbon sources including methane, carbon monoxide and acetylene.
Synthesis of carbon nanotubes by swirled floating catalyst. In 2007, researchers at the university of cincinnati uc developed a process to grow aligned carbon nanotube arrays of length 18 mm on a firstnano et3000 carbon nanotube growth system. Catalytic chemical vapor deposition synthesis of doublewalled and fewwalled carbon nanotubes by using a moo3supported conditioning catalyst to control the formation of iron catalytic particles within an. Growth of carbon nanotubes by chemical vapor deposition minjae junga, kwang yong eunb, jaekap leeb, youngjoon baikb, kwangryeol leeb, jong wan parka adepartment of metallurgy, hanyang uni ersity, 17, haengdangdong, seoul, 3791, south korea. The hydrocarbons flow through the quartz tube being in an oven at a high temperature 720 c. We have developed a new approach for preparing graphitic carbon nanofiber and nanotube ensembles. Such method is also a very important technique to in situ align carbon nanotubes. Huiling jin 1, jia jianjun 2, yishi su 1, shisheng li 1, qiubao ouyang 1, di zhang 1. Different aspects of cnt synthesis and growth mechanism are. D candidate department of chemical engineering mcgill university, montreal, canada introduction carbon nanotubes cnts are allotropes of carbon with a cylindrical nanostructure. Firstly, the growth windows for selectively synthesising high quality singlewalled carbon nanotubes via photothermal chemical vapour deposition ptcvd are determined. Chemical vapor deposition growth of singlewalled carbon.
Multiwalled carbon nanotubes cnts have been synthesized by chemical vapor deposition cvd from methane and carbon monoxide. Chemical vapor deposition of 3d graphenecarbon nanotubes. Nanotubes form in the arc and collect on the anode, along with a host of other carbon byproducts. Chemical vapor deposition cvd is the means of synthesis that is of interest for this study. Quantitative and controllable growth of carbon nanotubes. Schematic diagram of the chemical vapor deposition apparatus is shown in fig. Synthesis of carbon nanotubes by swirled floating catalyst chemical vapour deposition method article in journal of nanoscience and nanotechnology 79.